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Innovating Organocatalysis as Promising Trend in Oxidation Reactions with Molecular Oxygen

TitleInnovating Organocatalysis as Promising Trend in Oxidation Reactions with Molecular Oxygen
Publication TypeJournal Article
Year of Publication2015
AuthorsOpeida, IO
Short TitleSci. innov.
DOI10.15407/scine11.06.055
Volume11
Issue6
SectionThe World of Innovations
Pagination55-59
LanguageEnglish
Abstract

The prospects for innovative organocatalytic aerobic oxidation developed by IPOCC of the NAS of Ukraine have been outlined. The practice of oxidizing the hydrocarbons and 5-hydroxymethylfurfural with molecular oxygen under mild conditions has been improved by using the organic compound, N-hydroxyphthalimide, as key catalyst. For the oxidation of coal and substrates whole molecules are capable of keto-enol tautomerism, the use of dimethyl sulfoxide as a solvent is an innovative method that ensures the action of basic catalysts.
Keywords5 hydroxymethylfurfural, aerobic oxidation, coal, dimethyl sulfoxide, hydrocarbons, N hydroxyphthalimide, organocatalysis
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